Effect Of A Surface Active Pyrrole On The Conductivity Of Polypyrrole Composites

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Thermoelectric Properties of Flexible PEDOT:PSS/Polypyrrole

water (Solution I, the volume content of pyrrole monomer was 0.547%). A piece of the paper (3 3 cm) was soaked in Solution I, which was continuously stirred at 50 rpm for 30 min. The pyrrole monomer was absorbed onto the surface and even diffused into the bulk of paper. Then, 8.65 g of FeCl3 6H2O as

Polypyrrole-Grafted Coconut Shell Biological Carbon as a

Polypyrrole (PPy) is a well-known semiconducting polymer that offers high electrical conductivity, environmental stability, and biocompatibility. Hong et al. deposited PPy into the pores of wood-based activated carbon for sulfate removal [15]. Moreover, when PPy is coupled with carrier ions, such as Cl , ClO 4, NO 3

Immobilization of drugs and biomolecules on in situ

synthesized monomer was copolymerized with pyrrole (Py) in different ratios to obtain smooth and adherent copolymer coatings on the metal surface. Results suggest that among the different coatings obtained, pure active ester functionalized polypyrrole (PPyNSE) coating is smoother and more adherent than its different copolymers with pyrrole.

Vol. 3, Issue 9, September 2014 Electrical Conductivity

composites were prepared by sol-gel method and studied for the determination of electrical conductivity by using four-in-line probe dc electrical conductivity measurement instrument. II. MATERIALS AND METHODS The reagents used for the synthesis of the material were obtained from CDH, Loba Chemie, E- Merck and Qualigens (India Ltd.).

Development of conducting polymer based wearable supercapacitors

importantly, inherent highly flexible nature. Polypyrrole (PPy) has been extensively developed for flexible electrodes because of its outstanding flexibility and high conductivity. It is chosen as the target active material to fabricate wearable supercapacitors in this thesis.

Composite electrode materials based on conducting polymers

effect of monomer concentration on the morphology of the as prepared polypyrrole layers.In this respect, two polypyrrole samples were compared ETS 8 with the monomer conc. 0.1 M and ETS18 with the monomer conc. 0.05 M, prepared electrochemically at j = 0.6 mA/cm 2

2015 OPEN ACCESS nanomaterials - MDPI

Oct 16, 2015 where ip is the peak current (A), n is the number of electrons, A is the active surface area (cm2), D is the diffusion coefficient (cm2/s), C is the concentration (mol/cm3), and v is the scan rate (V/s). For determining the ratio of the PPy-MWCNTs/GCE to the bare GCE, i.e., the apparent surface active area, we need the

Effect of feeding ratios on the structure and electrochemical

the conducting polymers and composites that have been studied, polypyrrole (PPy) and its composites are among the most extensively studied. This is because they possess high electrical conductivity, interesting redox properties and rel-atively high environmental stability. Furthermore, PPy is easy to prepare via chemical or electrochemical

One-Step UV-Induced Synthesis of Polypyrrole/Ag

active sites on the silver particles so as to induce the growing polycationic PPy chains to complete the coating of PPy layers, resulting in the formation of PPy/Ag nano-composites. In addition, the effect of the feed ratio of Fig. 1 TEM images of PPy/Ag nanocomposites prepared at [AgNO 3]/[pyrrole] of 0.8 with (a) and without (b) of PVP

Heterogeneous interface induced formation of balsam pear-like

rated protrusions, just like the surface structure of balsam pear. The surface protrusions of SE-PPy can furnish a larger contact area between the electrolyte and the electrode, and thus effectively boost the accessible active sites for electrolyte ions and electrons. By contrast, the SP-PPy was spherical and relatively flat.

Defense Technical Information Center Compilation Part Notice

conducting polymers, with the high surface area and electrical conductivity of carbon nanotubes. Here we report the supercapacitive properties of a particular carbon nanotube-polypyrrole composite in which the conducting polymer is doped by the embedded nanotubes.

Investigation of Irradiation Effects on Conducting Composite

influenced the conductivity of PPy/Bnt composite. The conductivity results show that dominant conduction mechanisms were hopping for both PPy/Bnt composite and irradiated samples due to wide range of localized states present near the Fermi level. Key words: Polypyrrole, bentonite, conducting composite, gamma irradiation.

Polypyrrole Nanotubes Decorated with Gold Particles Applied

The novel composites of gold nanoparticles and polypyrrole nanotubes (Au x @PNT) were prepared and used as a platform for fabrication of bioelectrode interfaces. Changing the conditions of composite preparation caused variations in a gold architecture, electrical conductivity and a biocompatibility.

All‐Printed Solid‐State Microsupercapacitors Derived from

and additional Ag+ are adsorbed onto the surface of Ag NPs because of the conventional ion adsorbed effect (stage II).[36] The surrounding PPy short chains and pyrrole monomers react with Ag+ at the surface of silver NPs (active sites) to form PPy films; eventually, the [email protected] NCs are produced (stage III).

A stretchable and bendable all-solid-state pseudocapacitor

low production cost, and low weight [7]. Polypyrrole (PPy) is a popular conjugated polymer widely used in various appli-cations owing to its low cost, environmental stability, bio-compatibility, and simple fabrication method [8]. PPy is typically doped with cations to achieve higher conductivity [9 12]. Due to the volume change of polymer

Polypyrrole-hemin-reduce graphene oxide: rapid synthesis and

Apr 29, 2020 the pyrrole monomers adsorbed on the sheets were oxidized by GO, followed by the simultaneous polymerization-growth of PPY chains on the surface of the hemin-RGO (He-RGO). The formation mechanism of the PPY-He-RGO composite was proposed according to the characterization results. The active area of the PPY-He-RGO-modified electrode was 2 Mater

Journal of Ma terials Chemistry A - RSC Publishing Home

porous, reduced graphene oxides-polypyrrole-MnO 2 (RGO-PPy-Mn) composites with large specific surface area and high specific capacitance, which was deposited of two active materials (PPy and MnO 2) into the graphene network (Fig. 1). During the first hydrothermal process of the composite

Synergy Effect of Nanocrystalline Cellulose for the

from the electrode surface is to recover the electrode with triton X-100 as a surface active agent [37]. The analytical detection technique, immobilization method, as well as the activity and stability of the enzyme are important parameters that affect the biosensor performance [38].

Advances in sensors based on conducting polymers

decrease in conductivity, with electrophilic gases (NO 2, PCl 3, SO 2) having the adverse effect 22. Most of the widely studied CPs in gas sensing applications are polythiophene and its derivatives 23,24, polypyrrole 25,26 polyaniline and composites 27-29 of these polymers. b) pH Sensors Polyaniline has been found most suitable organic

Polypyrrole gold nanostructured composite, active and durable

present in polypyrrole gold composites and electrodeposited gold nanocrystals (PPY Au and Au NPs) with OH radicals generated in Fenton s reaction were investigated. Particularly, the changes in the morphology and the electrochemical prop-erties of those materials are shown. For both materials, the etching effect was noticed.

Capacitive properties of polypyrrole/activated carbon composite

that uses carbon-based active materials with a rela-tively high electronic conductivity, electrochemical sta-bility and acceptable cost [2,3]. The power and energy-storage capabilities of these devices are closely linked to the physical and chemical characteristics of carbon electrodes. For example increases in specific surface

Structural and Electrochemical Analysis of Microwave-Assisted

macroporous system. Liu [35] prepared graphene/polypyrrole nanocomposite with the conductivity of 1980 S m-1. Bora [36] developed sulfonated graphene/polypyrrole nanocomposite by interfacial polymerization. In this report, the composites of graphene and polypyrrole are synthesized by modified hummers' method, and in situ polymerization method.

Studying the Characteristics of Polypyrrole and its Composites

Abstract: Polypyrrole and its composites were prepared chemically using FeCl 3 as an oxidant in aqueous and non-aqueous media. The effect of various solutions such as water, ethylacetate, acetonitrile, methylacetate, methanol, ethylmethylketone and surface active agents, poly (ethylene glycol) and poly

ARTICLE Alkali Treatment to Maximize Adhesion of Polypyrrole

carboxyl groups on PET surface by hydrolysis, and for-mation of PPy layer on the fabric surface 2. Experimental In the experimental process, a plain-weave polyethylene terephthalate (PET) fabric (95 g/m2, 40 warp/cm, 32 weft/ cm) was used. Sodium hydroxide (NaOH), hydrochloric acid (HCl), ethanol, and reagent grade pyrrole (Py) mono-

Effect of graphene oxide on the structural and

The increased electrical conductivity as much as 2.2 110 1 Scm for Ppy/GO/Cotton composite measured by complex impedance, is attributed to the formation of continuous conducting network. The partial reduction of GO on the surface of cotton (GO/ Cotton) during chemical polymerization can also affect the conductivity. This simple, economic and envi-

Synthesis and characterization of polypyrrole decorated

However, all reported RGO-PPy composites have been prepared using graphene oxide (GO) and pyrrole monomer as a staring material [31, 34 36]. The hydrophobic nature and abundant functional groups of GO are often more supportive to prepare RGO and PPy composites, yet the active surface area of the resulting composite is greatly abridged due to the

Corrosion protection with zinc-rich epoxy paint coatings

2.1. Synthesis of polypyrrole deposited alumina particles Fumed alumina (Evonik Industries AG, Germany) was dispersed in aqueous ethanol (50 ml) by vigorous stirring for 1 h. Pyrrole (Aldrich) was dissolved at a concentration of 2×10 2 mol dm 3 and the suspension stirred for 2 h. Solutions (10 ml) of iron(III) nitrate (Fluka) and nitric acid


surface electrical conductivity. Thus, the enhanced catalytic activity observed in our study may be ascribed, at least in part, to the Ni 0.3 Co 2.7 O 4 particle size which is smaller (higher surface area), or to its conductivity improvement.

Effect of Carbon Dots on Conducting Polymers for Energy

[email protected] composites. The composites of Cdots with conducting polymers (PPy and PANI) were synthesized using CTAB and APS.38 CTAB (124 mg, 0.01 M) was dissolved in aqueous 0.1 M hydrochloric acid solution (30 mL) under stirring, and as-synthesized Cdots solution (0.2, 0.5, or 1 mL) was mixed in this solution. Sequentially, pyrrole monomer

The preparation of polypyrrole Fe O nanocomposites by the use

The room temperature conductivity of PPy Fe3O4 composites was higher than that of pure PPy, and went on increasing as the Fe 3 O 4 content in the composites elevated, reaching a maximum at about

Polypyrrole Conducting Electroactive Polymers: Synthesis and

polymerisation of pyrrole appears to be a general and useful tool for the preparation of conductive composites21,22 and dispersed particles in aqueous media23,24. Iron (III) chloride has been found to be the best chemical oxidant and water is the best solvent for chemical polymerisation with respect to desirable conductivity

Cycling Performance of Supercapacitors Assembled with

improve the overall conductivity of the composite material. The advantage of adding conductive carbon into the polymerization system is that it can be coated with PPy, thus exposing more effective surface area of the active electrode material without any reduction in the bulk electronic conductivity of the composites. In a typical

Synthesis and Electrochemical Characterization of Polypyrrole

The effect of content of MWCNT in the composite on cycling performance of the cells is also investigated. Key Words: Cycling performance, Multi-walled carbon nanotubes, Nanocomposite, Polypyrrole, Superca-pacitor Table 1. Summary of reactant composition for synthesizing PPy/ MWCNT composites. PCNT-10 PCNT-20 PCNT-30 MWCNT (g) 0.100 0.210 0.325

ORIGINAL ARTICLE Open Access Facile synthesis and

Then, the conductivity has been measured by a DC voltage/current detector with four probe standard methods at room temperature. The data reported based on the average value of four measure-ments. The conductivity of nanocomposites has been il-lustrated vs. MWCNTs weight fraction in Figure 4. As can be seen, the conductivity increases by


issn: 09720626 volume 13, issue 03, september, 2020 423 effect of transition metal dopant on structural and thermal properties of polypyrrole

Chemical synthesis of polypyrrole doped with dodecyl benzene

coatings are very stable and thus used in carbon composites.10 Similarly corrosion of metals can also be prevented by the use of polypyrrole blends.11 Investigation of the structure, applications in technology, chemical and physical properties requires the synthesis of soluble -carbon of pyrrole

Integrated Conductive Hybrid Electrode Materials Based on PPy

presence of CFs via the in situ oxidation method, and then coated the PPy on the surface of composites to optimize the electrochemical performance. 2. Experiment 2.1. Materials and Reagents Cobalt nitrate, 2-methylimidazole, ammonium persulfate, and ferric chloride were of analytical grade and used as received. Pyrrole monomer was purified by

Electrochemical behaviour of pyridostigmine bromide-an

moderately high conductivity, low cost, relatively high stability and facile production by electrodeposition 23. Composites of PPy with polyethylene glycole, nafion, polyurethane, poly-vinyl chloride and with CMC has been reported extensively 24-27. The polyaniline polypyrrole composites 28 have conductivity in the range of 10-2 to

Facial In-situ Synthesis of MnO /PPy Composite for Supercapacitor

is an imperative task[13]. Polypyrrole (PPy) is known as one of the most frequently investigated important conducting polymers due to its high conductivity, easy-preparation, good environmental stability and no toxicity [14, 15]. It is expected that the combination of PPy and manganese dioxide will produce synergetic effect.